I would first read the What's New document for Python 3. It gives a good high-level overview and touches on the detailed changes.
You might also do a search for 'porting to python 3' or similar. There are lots of good resources and tools.
One tool that's new and hard to find is six, by Benjamin Peterson. It enables writing of code that is compatible across the Python 2*3 gap.
The part I found most difficult about maintaining Python 2 and Python 3 -compatible code was deployment. I could write code that would run just fine, but when I went do package and deploy, it was unclear when the conversion should happen. I ultimately found a distutils command build_py_2_to_3
that would do the trick. By using that command in my setup.py, I could release a source distribution that would deploy on either Python 2 or Python 3. An example can be found in jaraco.util.
You also asked about the internals. If you really want to get at the internals, you can view the source for Python 2.x and Python 3.x, though honestly, I would stick with reading the tutorials and maybe some of the .py files in the Python libs.