In my experience, I notice a difference more with age-groups, than with techie/non-techie status. I guess you could look at that in general terms of younger folks being more "techie" than older folks, but I wouldn't go so far as to call them "high-tech" -- they're just more comfortable with computers/internet because it's always been part of their lives.
The younger my customers are, the less concerned they seem to be with privacy / sharing their information with a "service" on the web, be it OpenID, Google, Facebook, or what have you. They also don't seem to mind having 2, 3 or even more email accounts with different providers.
The older my customers are, the less comfortable they become putting their info online (e.g.: even the bare minimum required to get an OpenID). There are enough horror stories in the news about privacy-related issues -- be it advertisers, hackers, or government subpoenas getting a hold of their information, etc. It isn't that they know something bad will happen -- it's that they know they have no idea how to spot a fraudulent service, evaluate risks or protect themselves -- it all seems so complicated, so they make the conservative choice not to put their information "out there" at all. Some of my older customers will give it a go, but even then, I also see a lot of reluctance in this group to setup more than one email account -- they use the one that their ISP provides, and won't use anything else.
Anyway -- those comments are just about who is more or less willing to use something like OpenID. Of those who are willing (of my users, I'd say about 85% below age 40 will use it; I can count on about 60-70% of my working-adult customers in general to use it; And my retiree users are at about 20%). I have only a few complaints in the "willing" groups about usability.