The only features that jruby has which C ruby does not are that you can access java libraries (on the other hand C extensions can be used with C ruby, but not with jruby, naturally) and that you can compile your code to .class-files. Jruby doesn't have any language features that C ruby doesn't have.
To answer your question: it's doubtful that the C ruby interpreter will ever allow you to call java libraries or include an option to compile to java bytecode.
As a sidenote: You don't need to know java to use jruby. Unless you're using C extensions, any ruby code that runs on C ruby should run on jruby without modifications. You also don't need to know any java to use java libraries from jruby, though you should obviously know the API of the library you're using.