JW answered my question at the tts-for-android group:
Hi Greg,
The Pico engine recognizes the tag with the XSAMPA alphabet.
There are no easy rules to derive a certain pronunciation from the orthograpy, but you can use intuitive spellings and trial and error. Capitalizing and hyphens will introduce more problems than solving them. Using different spellings and introducing extra word boundaries (spaces) can work.
The emphasis tag and the exclamation mark will not change the synthesis result. Use , , and commands instead.
Some examples of the proper syntax for specifying the pronunciation using the SSML phoneme tag are in these tests of TextToSpeech.
Even with these simple test SSML documents, there are warning messages posted to logcat about the SSML document not being well-formed. So I opened an issue about these seemingly incorrect logcat messages to the Android issue tracker.
The syntax for specifying an x-SAMPA sequence to SVOX pico is
String text = "<speak xml:lang=\"en-US\"> <phoneme alphabet=
\"xsampa\" ph=\"d_ZIn\"/>.";
mTts.speak(text, TextToSpeech.QUEUE_ADD, null);
Although more examples would be helpful, a good reference for x-SAMPA is at http://en.wikipedia.org/wiki/Xsampa If I compile a couple dozen examples, I'll post them to that Wikipedia page.