My snow leopard only has python 2.5 and 2.6 installed, so it's not that many. You may have additional pythons installed (i.e. python3.0), either system wide (in /usr/bin/) or through macports (/opt/local).
The default system python is defined through a setting,
defaults write com.apple.versioner.python Version 2.5
will change the default to 2.5. You can also use an environment variable, i.e. for bash:
export VERSIONER_PYTHON_VERSION=2.5
All of this is documented in the python manpage,
man python
Overall, it's better not to change the system default. It's what OSX may depend on for certain scripts, and you never know if these scripts work as expected on different versions. Especially Python 3 is different, and may really break your whole system.
If you want a different python to be used for your own scripts, either
- Use virtualenv (always good)
- Change your PATH and make sure your preferred python is included before the /usr/sbin one
- Be explicit, invoke the script using /my/preferred/python