ASP.NET's server-side controls work with WebForms, not MVC. MVC doesn't use controls in the traditional ASP.NET sense (at least yet).
The MVC model is quite different from the WebForms model; not better or worse, but very different. Using MVC puts the developer much closer to the generated HTML, lends itself more intrinsically to unit testing, and provides a strong separation of concerns between the UI and the code that populates that UI.
At first glance, especially to hardened ASP.NET veterans, MVC can seem like a huge step backwards (if you've were coding then, visions of ASP COM development might dance in your head).
But give MVC a try. It is very interesting and its model is quite compelling once you get used to it.
Read more here:
http://quickstarts.asp.net/previews/mvc/mvc_HowToRenderFormUsingHtmlHelpers.htm
Also, check out this interesting blog engine that uses MVC:
http://www.codeplex.com/oxite
Finally, check out Rob Conery's MVC storefront project:
http://blog.wekeroad.com/mvc-storefront/mvc-storefront-part-1/