If you have a double-quoted string then it can't contain unescaped double-quotes (for, hopefully, obvious reasons).
Some ways to get around it:
1/ Escape the double quotes.
print "<tr style='background-color:#CDC9C9;'>
<td><A HREF=\"http://localhost/cgi-bin/AddUser.cgi\">ADD</A></td>
<td></td>
<td><b>UserId</b></td>
<td><input type=\"text\" name=\"UserId\"></td>
<td><b>UserName</b></td>
<td><input type=\"text\" name=\"User_Name\"></td>
<td><input type=\"submit\" name=\"Filter\" value=\"Filter\"> </td>
</tr>";
2/ Switch to a single-quoted string (as your string contains no variables or escape sequences).
print '<tr style="background-color:#CDC9C9;">
<td><A HREF="http://localhost/cgi-bin/AddUser.cgi">ADD</A></td>
<td></td>
<td><b>UserId</b></td>
<td><input type="text" name="UserId"></td>
<td><b>UserName</b></td>
<td><input type="text" name="User_Name"></td>
<td><input type="submit" name="Filter" value="Filter"> </td>
</tr>';
Note: I had to change the single quotes in the style attribute to double quotes here.
3/ Use a here-doc.
print <<END_OF_HTML;
<tr style='background-color:#CDC9C9;'>
<td><A HREF="http://localhost/cgi-bin/AddUser.cgi">ADD</A></td>
<td></td>
<td><b>UserId</b></td>
<td><input type="text" name="UserId"></td>
<td><b>UserName</b></td>
<td><input type="text" name="User_Name"></td>
<td><input type="submit" name="Filter" value="Filter"> </td>
</tr>
END_OF_HTML
4/ Choose a different quoting character.
print qq[<tr style='background-color:#CDC9C9;'>
<td><A HREF="http://localhost/cgi-bin/AddUser.cgi">ADD</A></td>
<td></td>
<td><b>UserId</b></td>
<td><input type="text" name="UserId"></td>
<td><b>UserName</b></td>
<td><input type="text" name="User_Name"></td>
<td><input type="submit" name="Filter" value="Filter"> </td>
</tr>];
But like so many of your problems, the real solution is to use a templating system.