You need to post your form to a servlet and from servlet execute this method to send mail.
your form should be
<form action="sendMail.do" method="post" enctype="text/plain" >
FirstName:<input type="text" name="FirstName">
Email:<input type="text" name="Email">
<input type="submit" name="submit" value="Submit">
</form>
Here is code to send email from java,do proper mapping for servlet in web.xml
For servlet tutorials check it here
import javax.mail.*;
import javax.mail.internet.*;
import java.util.*;
public void postMail( String recipients[ ], String subject, String message , String from) throws MessagingException
{
boolean debug = false;
//Set the host smtp address
Properties props = new Properties();
props.put("mail.smtp.host", "smtp.jcom.net");
// create some properties and get the default Session
Session session = Session.getDefaultInstance(props, null);
session.setDebug(debug);
// create a message
Message msg = new MimeMessage(session);
// set the from and to address
InternetAddress addressFrom = new InternetAddress(from);
msg.setFrom(addressFrom);
InternetAddress[] addressTo = new InternetAddress[recipients.length];
for (int i = 0; i < recipients.length; i++)
{
addressTo[i] = new InternetAddress(recipients[i]);
}
msg.setRecipients(Message.RecipientType.TO, addressTo);
// Optional : You can also set your custom headers in the Email if you Want
msg.addHeader("MyHeaderName", "myHeaderValue");
// Setting the Subject and Content Type
msg.setSubject(subject);
msg.setContent(message, "text/plain");
Transport.send(msg);
}