"" is an empty string containing no characters. There is no "empty character", unless you mean a space or the null character, neither of which are empty strings.
You can think of a string as starting with an infinite number of empty strings, just like you can think of a number as starting with an infinite number of leading zeros without any change to the meaning.
1 = ...00001
"foo" = ... + "" + "" + "" + "foo"
Strings also end with an infinite number of empty strings (as do decimal numbers with zeros):
1 = 001.000000...
"foo" = "foo" + "" + "" + "" + ...