I don't think it is possible in the way you want it because the presence of contacts (which contains the information about their availability) is received asynchronously by the bot.
You will have to write a presence handler function and registered it with the connection. This function will get called whenever a presence is received from a contact. The parameter of the call will tell you if the contact is online or not. Depending upon it you can send the message to the contact.
Using xmpppy
you do it something like this:
def connect(jid, password, res, server, proxy, use_srv):
conn = xmpp.Client(jid.getDomain())
if not conn.connect(server=server, proxy=proxy, use_srv=use_srv):
log( 'unable to connect to server.')
return None
if not conn.auth(jid.getNode(), password, res):
log( 'unable to authorize with server.')
return None
conn.RegisterHandler( 'presence', callback_presence)
return conn
conn = connect(...)
def callback_presence(sess, pres):
if pres.getStatus() == "online":
msg = xmpp.Message(pres.getFrom(), "Hi!")
conn.send(msg)
PS: I have not tested the code but it should be something very similar to this.