They are equivalent in function, though the compilers I tested (Java 1.6.0_07 and Eclipse 3.4) generate different bytecode. The first generates:
// access flags 33
public synchronized someMethod()V
RETURN
The second generates:
// access flags 1
public someMethod()V
ALOAD 0
DUP
MONITORENTER
MONITOREXIT
RETURN
(Thanks to ASM for the bytecode printing).
So the difference between them persists to the bytecode level, and it's up to the JVM to make their behavior the same. However, they do have the same functional effect - see the example in the Java Language Specification.
It should be noted, that if the method is overridden in a subclass, that it is not necessarily synchronized - so there is no difference in that respect either.
I also ran a test to block a thread trying access the monitor in each case to compare what their stack traces would look like in a thread dump, and they both contained the method in question, so there is no difference there either.