What you certainly are going to need is a much better feel for hardware. From a software perspective you'll need to understand things like interrupts and registers. You're also going to need to know at least some basic electronics like resistors, capacitors and how to read a basic schematic.
Before diving into a high-level abstraction like Robotics Studio, I'd recommend getting an embedded development kit that targets what you already know to at least make the learning curve more gentle. If you know C/C++, then there are loads of dev kits for all sorts of microcontrollers out there (I really like the PIC learning kits from CCS). If you're a VB guy, then Parallax has a great selection of BASIC Stamp stuff. If you're a C# guy, then there are .NET Micro Framework kits (with a wide array of features and prices).
The basic idea is to get a kit and learn how to do things like turn on LEDs, drive servos, etc. Get you feet wet and see if you like it and have an aptitude for it. Once you're there, you can start adding on to what you have with peripherals, more complex kits or whatever strikes your interest (including investigating the Robotics Studio deeper).
Of course there's a whole separate software side in industrial robotics with PLCs, etc. but the cost to even get into that game is high, so you'd want to attend a formal school that provides you access to robots and dev tools like RSLogix.
I've done work in both sides. I spent several years writing drivers and kernels for CE systems at a hardware OEM, so that's where I learned to read schematics, how to deal with interrupts, drivers, etc.
I've always been interested in the hobby side, so I've done work with lots of PIC stuff in my free time as well as several Micro Framework kits. Expereince there is largely from free time spent playing with those. Having a solid CE app resume and that knowledge got me the job running the CE department for the OEM.
Now I do less low-level CE work, but a lot more PLC work. That was driven by a project where we wrote a solution that interfaced the two - a CE device communicating with PLCs on a plant floor.
It was all organic to get there, but it started with an interest in writing software for handhelds (CE, PalmOS, RIM) and ended up interfacing with industrial controls on a factory floor.