I agree that it's counterintuitive at first, but there's a good reason. Join can't be a method of a list because:
- it must work for different iterables too (tuples, generators, etc.)
- it must have different behavior between different types of strings.
There are actually two join methods (Python 3.0):
>>> b"".join
<built-in method join of bytes object at 0x00A46800>
>>> "".join
<built-in method join of str object at 0x00A28D40>
If join was a method of a list, then it would have to inspect its arguments to decide which one of them to call. And you can't join byte and str together, so the way they have it now makes sense.