If I understand correctly and you are trying to look at non-matching parenthesis in C code (that was generated in python), I would recommend you install rainbow.vim from Dr Chip's Site. This will highlight braces in different colours depending on the levels of indentation and will highlight unmatching braces in red as you have requested. A screenshot is at http://img294.imageshack.us/img294/8586/rainbow.jpg.
To install, download rainbow.vim and place in vimfiles/after/syntax/c/ (create this directory if it is not present).
On Linux, this will be ~/.vim/after/syntax/c/rainbow.vim
On Windows, it may be c:\vim\vimfiles\after\syntax\c\rainbow.vim or possibly somewhere else, see ":help runtimepath".
Note that there are some plugins that conflict with rainbow.vim, but it's not too hard to make them cooperate.
If you are trying to highlight non-matching parenthesis in the python code, you could modify rainbow.vim to use the python syntax clusters instead of the C ones, but this is a little more involved, but you could use something along the lines of (modified version of Dr Chip's rainbow code):
syn cluster pyParenGroup contains=pythonString,pythonRawString,pythonEscape,pythonNumber,pythonBuiltin,pythonException
syn match pyParenError display ')'
syn region pyParen transparent matchgroup=hlLevel0 start='(' end=')' contains=@pyParenGroup,pyParen1
syn region pyParen1 transparent matchgroup=hlLevel1 start='(' end=')' contains=@pyParenGroup,pyParen2
syn region pyParen2 transparent matchgroup=hlLevel2 start='(' end=')' contains=@pyParenGroup,pyParen3
syn region pyParen3 transparent matchgroup=hlLevel3 start='(' end=')' contains=@pyParenGroup,pyParen4
syn region pyParen4 transparent matchgroup=hlLevel4 start='(' end=')' contains=@pyParenGroup,pyParen5
syn region pyParen5 transparent matchgroup=hlLevel5 start='(' end=')' contains=@pyParenGroup,pyParen6
syn region pyParen6 transparent matchgroup=hlLevel6 start='(' end=')' contains=@pyParenGroup,pyParen7
syn region pyParen7 transparent matchgroup=hlLevel7 start='(' end=')' contains=@pyParenGroup,pyParen8
syn region pyParen8 transparent matchgroup=hlLevel8 start='(' end=')' contains=@pyParenGroup,pyParen9
syn region pyParen9 transparent matchgroup=hlLevel9 start='(' end=')' contains=@pyParenGroup,pyParen
hi link pyParenError Error
if &bg == "dark"
hi default hlLevel0 ctermfg=red guifg=red1
hi default hlLevel1 ctermfg=yellow guifg=orange1
hi default hlLevel2 ctermfg=green guifg=yellow1
hi default hlLevel3 ctermfg=cyan guifg=greenyellow
hi default hlLevel4 ctermfg=magenta guifg=green1
hi default hlLevel5 ctermfg=red guifg=springgreen1
hi default hlLevel6 ctermfg=yellow guifg=cyan1
hi default hlLevel7 ctermfg=green guifg=slateblue1
hi default hlLevel8 ctermfg=cyan guifg=magenta1
hi default hlLevel9 ctermfg=magenta guifg=purple1
else
hi default hlLevel0 ctermfg=red guifg=red3
hi default hlLevel1 ctermfg=darkyellow guifg=orangered3
hi default hlLevel2 ctermfg=darkgreen guifg=orange2
hi default hlLevel3 ctermfg=blue guifg=yellow3
hi default hlLevel4 ctermfg=darkmagenta guifg=olivedrab4
hi default hlLevel5 ctermfg=red guifg=green4
hi default hlLevel6 ctermfg=darkyellow guifg=paleturquoise3
hi default hlLevel7 ctermfg=darkgreen guifg=deepskyblue4
hi default hlLevel8 ctermfg=blue guifg=darkslateblue
hi default hlLevel9 ctermfg=darkmagenta guifg=darkviolet
endif
EDIT:
As a test, I downloaded gvim70.zip and vim70rt.zip from ftp://ftp.vim.org/pub/vim/pc/ (these are the Windows versions of Vim 7.0). I unzipped the two files into a new directory and ran gvim.exe from vim/vim70/gvim.exe. I do not have any vim configuration stored in "C:\Documents and Settings", so running this vim is the same as running a 'vanilla' configuration. I then downloaded pyprint.py from http://www.amk.ca/python/simple/pyprint.html as a piece of sample code and copied the above code into a file called code.vim. In gVim, I entered ":e pyprint.py". It opened in the white-background window, with no syntax highlighting. I then entered ":syntax on", which switched the default syntax highlighting on. I added a second ')' character on line 8. Finally, I entered ":source code.vim", which made the second ')' character be highlighted in red.
I've also carried out this test on Linux (with Vim 7.2), by entering the following command sequence:
cd ~
mv .vimrc old_dot_vimrc
mv .gvimrc old_dot_gvimrc
mv .vim old_dot_vim
vim pyprint.py
:e pyprint.py
" Add extra bracket here!
:syntax on
:source code.vim
Again, the second bracket is highlighted and everything else seems normal.