Sounds like something you'd need to attach to a form, or specific links. If the event is raised by a link, and there is a request string full of variables, it will act as a GET. If it's a form, you'll have to check the METHOD, and then figure the URL based on the data being submitted in the form itself.
<a href="thisPage.php">No method</a>
<a href="thisPage.php?usrName=jonathan">GET method</a>
<form method="GET" action="thisPage.php">
<!-- This is a GET, according to the method -->
<input type="text" name="usrName" value="jonathan" />
</form>
<form method="POST" action="thisPage.php">
<!-- This is a POST, according to the method -->
<input type="text" name="usrName" value="jonathan" />
</form>
So the detection would take place not in the window method, but in the click method of your links, and form submissions.
/* Check method of form */
$("form").submit(function(){
var method = $(this).attr("method");
alert(method);
});
/* Check method of links...UNTESTED */
$("a.checkMethod").click(function(){
var isGet = $(this).attr("href").get(0).indexOf("?");
alert(isGet);
});