Make up a list of things you can show them increasing in complexity - more than 3 hours of material.
When they arrive, gauge their level of understanding and interest and adapt.
I don't know what business you're in, but if you want to do well, try to come up with a few different topics to focus on in terms of what might be interesting to them.
For instance, get the list of cars from fueleconomy.gov for car enthusiasts, or grab a list of players for NBA, NFL, NHL, etc and pre-populate databases so you can riff off of something they have an interest in.
If possible, use tools and techniques they can do at home and even consider making a CD with free software and the results of your hour of exploration.
The web is a very interesting place, and showcases your skills very well for instance. There are now free web hosts which support MySQL and PHP - they aren't great, but they're cheap. You might consider doing very simple PHP and MySQL websites for each of them.