Last time I hired a new co-worker, he only had experience in PHP, he even had quit school and was very young, so his actual experience was limited, given his years of work in the field. Based on these facts, would you hire this person? Most peoples first thought would be probably not.
Well, today he's not just a PHP developer, but went from Lucene over to Solr and nowadays he even develops internal Plug-Ins for the latter and is in general also our Java-Wit, Maven Guru and lays the foundation when we need internal tools, for various reasons, in Java.
So what's the deal with PHP here? He fluently writes it like Java, sometimes you can't distinguish one from the other. Adopting to unknown things, like working into Zend Framework stuff, is natural to him.
But then, he has programming as his hobby (which many have, I guess), too. Writing stuff like compilers in his spare time, etc. Quick adopter, I would call that.
On the other hand, I'm really preparing myself for interviews, discussing with other co-workers things which are relevant and observe people reacting to certain questions in the interview.
Oh, and you as a an interviewer need also one thing badly: luck.