If you're doing your design / coding in C# classes, adorned with [ServiceContract] and [OperationContract], then I don't know of any way to export documentation you might have on those classes and methods into the WSDL, unfortunately.
I was appalled by that too - I expected any /// comments on my classes and methods to show up in the WSDL - no luck :-(
Our solution now is this:
1) we create a basic "mockup" of our service interface with all operations in C#
2) we compile that into an assembly
3) we extract the metadata (WSDL, XSD) from that assembly and then throw away the C# "prototype"
4) we manually add comments (xs:annotation/xs:documentation) to the WSDL and XSD
5) from now on, the WSDL/XSD are the master - and we generate our interface from those descriptions
Cumbersome and annoying, but it works fairly ok for us.
I sure hope VS2010 / WCF 4.0 will bring us a bit more support in this area !!
Marc