Mac OS X ships with apache pre-installed, but the files are in non-standard locations. This question is a place to collect information about where configuration files live, and how to tweak the apache installation to do things like serve php pages.
Apache Config file is: /private/etc/apache2/httpd.conf
Default DocumentRoot is: /Library/Webserver/Documents/
To enable PHP, at around line 114 (maybe) in the /private/etc/apache2/httpd.conf file is the following line:
#LoadModule php5_module libexec/apache2/libphp5.so
Remove the pound sign to uncomment the line so now it looks like this:
LoadModule php5_module libexec/apache2/libphp5.so
Restart Apache: System Preferences -> Sharing -> Un-check "Web Sharing" and re-check it. OR
$ sudo apachectl restart
httpd.conf is in /private/etc/apache2
Enable PHP by uncommenting line:
LoadModule php5_module libexec/apache2/libphp5.so
Running
$ httpd -V
will show you lots of useful server information, including where the httpd.conf file can be found.
/etc/httpd/users contains user-specific configuration files which can be used to override the global configuration. For example, adding "AddHandler server-parsed html" to the <Directory> block in the /etc/httpd/users/*.conf file that corresponds to one user will enable mod_include parsing of HTML files for that particular user's $HOME/Sites directory, but nowhere else.