Unfortunately, this is not possible with the default Django template engine. You'll have to write something ugly like this to emulate a switch.
{% if a %}
{{ a }}
{% else %}
{% if b %}
{{ b }}
{% else %}
{% if c %}
{{ c }}
{% else %}
{{ default }}
{% endif %}
{% endif %}
{% endif %}
or if only one if condition can be true and you don't need a default.
{% if a %}
{{ a }}
{% endif %}
{% if b %}
{{ b }}
{% endif %}
{% if c %}
{{ c }}
{% endif %}
Usually, when the template engine is not powerful enough to accomplish what you want this is a sign that the code should be moved into Django view instead of in the template. For example:
# Django view
if a:
val = a
elif b:
val = b
elif c:
val = c
else:
val = default
# Template
{{ val }}