If you use a try/catch block a raiserror error number with severity 11-19 will cause execution to jump to the catch block.
Any severity above 16 is a system error.  To demonstrate the following code sets up a try/catch block and executes a stored procedure that we assume will fail:
assume we have a table [dbo].[Errors] to hold errors
assume we have a stored procedure [dbo].[AssumeThisFails] which will fail when we execute it
-- first lets build a temporary table to hold errors
if (object_id('tempdb..#RAISERRORS') is null)
 create table #RAISERRORS (ErrorNumber int, ErrorMessage varchar(400), ErrorSeverity int, ErrorState int, ErrorLine int, ErrorProcedure varchar(128));
-- this will determine if the transaction level of the query to programatically determine if we need to begin a new transaction or create a save point to rollback to
declare @tc as int;
set @tc = @@trancount;
if (@tc = 0)
 begin transaction;
else
 save transaction myTransaction;
-- the code in the try block will be executed
begin try
 declare @return_value = '0';
 set @return_value = '0';
 declare
  @ErrorNumber as int,
  @ErrorMessage as varchar(400),
  @ErrorSeverity as int,
  @ErrorState as int,
  @ErrorLine as int,
  @ErrorProcedure as varchar(128);
 -- assume that this procedure fails...
 exec @return_value = [dbo].[AssumeThisFails]
 if (@return_value <> 0)
  raiserror('This is my error message', 17, 1);
 -- the error severity of 17 will be considered a system error execution of this query will skip the following statements and resume at the begin catch block
 if (@tc = 0)
  commit transaction;
 return(0);
end try
-- the code in the catch block will be executed on raiserror("message", 17, 1)
begin catch
  select
   @ErrorNumber = ERROR_NUMBER(),
   @ErrorMessage = ERROR_MESSAGE(),
   @ErrorSeverity = ERROR_SEVERITY(),
   @ErrorState = ERROR_STATE(),
   @ErrorLine = ERROR_LINE(),
   @ErrorProcedure = ERROR_PROCEDURE();
  insert #RAISERRORS (ErrorNumber, ErrorMessage, ErrorSeverity, ErrorState, ErrorLine, ErrorProcedure)
   values (@ErrorNumber, @ErrorMessage, @ErrorSeverity, @ErrorState, @ErrorLine, @ErrorProcedure);
  -- if i started the transaction
  if (@tc = 0)
  begin
   if (XACT_STATE() <> 0)
   begin
     select * from #RAISERRORS;
    rollback transaction;
    insert into [dbo].[Errors] (ErrorNumber, ErrorMessage, ErrorSeverity, ErrorState, ErrorLine, ErrorProcedure)
     select * from #RAISERRORS;
    insert [dbo].[Errors] (ErrorNumber, ErrorMessage, ErrorSeverity, ErrorState, ErrorLine, ErrorProcedure)
     values (@ErrorNumber, @ErrorMessage, @ErrorSeverity, @ErrorState, @ErrorLine, @ErrorProcedure);
    return(1);
   end
  end
  -- if i didn't start the transaction
  if (XACT_STATE() = 1)
  begin
   rollback transaction myTransaction;
   if (object_id('tempdb..#RAISERRORS') is not null)
    insert #RAISERRORS (ErrorNumber, ErrorMessage, ErrorSeverity, ErrorState, ErrorLine, ErrorProcedure)
     values (@ErrorNumber, @ErrorMessage, @ErrorSeverity, @ErrorState, @ErrorLine, @ErrorProcedure);
   else
    raiserror(@ErrorMessage, @ErrorSeverity, @ErrorState);
   return(2); 
  end
  else if (XACT_STATE() = -1)
  begin
   rollback transaction;
   if (object_id('tempdb..#RAISERRORS') is not null)
    insert #RAISERRORS (ErrorNumber, ErrorMessage, ErrorSeverity, ErrorState, ErrorLine, ErrorProcedure)
     values (@ErrorNumber, @ErrorMessage, @ErrorSeverity, @ErrorState, @ErrorLine, @ErrorProcedure);
   else
    raiserror(@ErrorMessage, @ErrorSeverity, @ErrorState);
   return(3);
  end
 end catch
end