The URLs of your pages denote the identity of the content. In my view, if the content is the same but the presentation varies (i.e RIA vs. HTML), then the URL should be the same and you should use some other mechanism to select between the different presentation forms. Choices of other mechanisms include cookies, content negotiation, session identifiers or, if your users are identified, a persistent user preferences model. Even using a URL argument would at least keep the root of the URL consistent (e.g. http://your.si.te/foobar
vs. http://your.si.te/foobar?view=plain
)
If the content of the two presentations differs in some meaningful way, then you should make that difference meaningful in the URL. Exploiting the presence or absence of #, and other such hacks, would be a mistake in my view.
Try to pick URL's that do not change over time: so-called cool URL's. This will aide the long-term usefulness of your site to your users: consider what happens if they come back to a bookmarked page in a year's time. Consistency will also help you to get a better critical mass of links or reviews of your site in del.icio.us and similar bookmarking/review sites.
Ian