You already have the two most important resources: The PHP site and the php|Architect study guide. The book is a little short on the details you will need to know, but it will show you were you need to study. If you aren't familiar with a section in the book, you can be assured the test will be much more in depth and specific.
I cannot recommend the php|Architect practice tests enough. After the first practice test or two I determined where I was weak and built a study program for those areas. I took detailed notes of everything I was unfamiliar with and tracked my progress on each section after each test. (They give you an excellent, pass, fail rating for each section.) After about five tests I was satisfied with my progress and took the test and passed. I ultimately think the best resource you can create is your own. I had about eight double-column, legal-pad pages of notes and topics that I eventually compressed into one type sheet which I studied relentlessly before the test.
I really believe you must have a long association with PHP to get certification. There are some items that I only knew because I started developing with PHP in 2001 and knew the php.net documentation intimately. Also, remember that you are studying for PHP 5, so topics like XML, OOP and other new features are heavily featured. I hope this helps and good luck!