I suspect there's two separate questions being asked in this thread which may not be related to each other.
Anyway, for the first question: You could reuse your existing template for your old website and adapt it into your custom Wordpress theme. Though I would say that theme development from scratch could be quite involved. If you don't like the learning curve of doing a Wordpress theme, you could opt to use an existing Wordpress theme and create a custom CSS to make it look like your existing webpage. I personally recommend that you could get a plain vanilla Wordpress theme like Sandbox and work the CSS from there.
As for the second question, if you are asking in the context of migrating your existing site to Wordpress: Wordpress automatically will generate the RSS feeds so long you port your pages into their "Posts" and "Pages" mechanism.
Do let us know and provide more information on what you want to achieve if you are asking the last question on a different context as in you have a set of webpages which you are not migrating to Wordpress but needing a means of needing an automatic means to translate those existing pages into a dynamic RSS feed.