You are not supposed to use the low-level API directly. It exists for framework developers to create high-level libraries on top of it. The documentation is aimed at those people (basically there is just JavaDoc).
Google officially supports the JDO and JPO frameworks (which are Java standards, but not necessarily a good fit for the non-relational data store (*) ), but there are a couple of alternatives "closer to the metal", that promise to be easier to understand, more light-weight and faster.
See objectify, twig, SimpleDS, and also this question.
Featurewise, there are a few things that the alternative libraries offer. For example, access to the underlying data store entities gives you binary representations that you can memcache without the class being serializable. You have fine-grained access over indexing (you could do partial indexes), and Twig also gives you asynchronous queries, which could be useful.
(*) There is also a bit of a backlash against JDO/JPA because it contributes to a few seconds of startup time, which is important on App Engine because Google shuts down your JVM after just a few minutes of inactivity, and the next user gets to wait ten seconds or more. However, I believe that is a fundamentally flawed argument, because when you are using Java, you want to use frameworks like JDO or Spring. Google even advertises like that. If these frameworks (especially the ones endorsed by Google itself) cannot be reasonably used on App Engine, then Google needs to fix that, not the framework authors.