You should be able to do asynchronous overlapped IO.
To get you started, look at the WriteFile win32 API call. It discusses how to use CreateFile with the FLAG_FILE_OVERLAPPED flag. You then call WriteFile and pass in an OVERLAPPED parameter, which contains the offset to start writing at and an event handle, which gets signaled when the IO is complete.
Alternativally, you can call WriteFileEx, which calls a function that you supply when the IO is complete, rather than signaling an event.
Note that you should write in blocks of 4K (4096) bytes rather then in blocks of 100 bytes, since this is the size of page files in Windows; it will speed up your IO considerably. Also note that this should only require one file handle, rather than multiple.