Since it is C the call to DebugBreak() is correct - this will give you a nasty error dialog (different look depending on the OS), which should have a 'Debug' option. If you click this you should get a dialog to select one of the installed debuggers (VS.NET shoud be among them). Selecting it should bring you to the DebugBreak() line. However this can fail if the debugger can not find the pdb files for your app - in that case you will just get the disassembly view and no source code view.
You can also use WinDBG and the 'Open executable option' - again it will need the pdb files to yield anything useful.