If you mean "can I change my xcdatamodel and just merge changes from the generated code into my existing code for the NSManagedObject derived classes," yes, that is simple. You just generate the code for the models that have changed then merge the changes by hand into those particular derived classes. Since the changes sound like they're just additional attributes and relationships, this should be trivial - in fact, you can probably use diff and patch to do this semi-automatically if your changes are truly additive in nature.
However, if you mean you need to migrate an existing store to a new schema, you have some work ahead of you. There are certain conditions (adding orthogonal entities, fetched properties, etc) that won't force you to do this. You will realize if you need to or not when you try to add your existing persistent stores to the persistent store coordinator for your managed object context.
Before you decide to embark on doing a schema change, you should always read up on how to do migrations and versioning in Core Data - if you have existing stores you need to retain. This is almost assuredly the case in apps that have user data stored in Core Data stores. And unless you have an automated import tool or data store generation utility your existing static stores are also likely to need migration.