I am not sure there is a clear an definitive answer to that question...
It's something that has been debated quite a couple of times already, I'd say... So you might want to take a look at some of these questions/answers (pretty random selection, I have to admit!) :
And, more generally, a search on php+framework might get you interesting stuff ;-)
Now, what would I do / choose ?
Well, the framework I know the best is Zend Framework... So I think (at least, without knowing more about your project) I would go with Zend Framework.
Why ? Because the time required to learn a framework is important ; might take a couple of weeks to know a framework "quite well", and a couple of months to "master it"... So, if you already know a framework, starting from scratch with another one might not be a wise idea.
If you don't know any framework... Well, invest something like 2 weeks studying the most important ones, doing some small prototype : this is the best way to see what they can do, how they can help you work, and decide wisely ;-)
And do not do that alone : work with a colleague : being two to do that kind of stuff / take that kind of decision is always better : you can learn from each other, and confront your opinions!
Yes, it's long, yes it's a bit costly... But if it's a decision that will impact the next couple of years for your company, it is definitly worth investing some time before deciding, and not rush that decision!
Some will say "but this one answers to 5 req/s more that the other one"... And so what ?
If you have a big application, you will most likely use some kind of cache ; maybe/probablye even multiple layers of cache... This (your caching strategy) is what will make the difference -- probably not the few differences in base performance between a couple of frameworks!