It depends on the Database you are using. If you are using Oracle, something like this will work:
Step 1: Find out max value of userid in your table:
select max(userid) from tbl_userid
let this number be m
Step 2: Find out the max value of rownum in the foll query
select rownum from all_objects
Step 3: If the max value is greater than m then you can use the foll query to list your unused user ids
select user_id
from tbl_userid
where user_id NOT IN (select rownum from all_objects)
If max value returned by step 2 is less than m you can tweak your query to the following
select user_id
from tbl_userid
where user_id NOT IN
(select rownum
from (select *
from all_objects
UNION ALL
select * from all_objects)
)
Repeat the UNION ALL until you get max(rownum) >= m
If you are using SQL server, kindly let me know. There is no direct equivalent of ROWNUM pseudocolumn in sql server but there are workarounds using the RANK() function.