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I programmed assembly on a Mac. It was Motorola 680x0 assembler using MPW. I've touched on the PowerPC assembler a few times in CodeWarrior and ProjectBuilder. Now ProjectBuilder is called XCode, and there is Intel. The assembler is one of the many tools within XCode.
I originally learned assembler on the Apple II: the 6502 machine language monitor built in ROM, the Sweet16 mini-assembler, and others. Later, I used Intel 80186 assembler to speed up slow bits of C code, and work paid for a one day course on Intel 80186 assembler at a university. Later, I had to maintain some 680x0 assembly for the Mac. That was a long time ago.
I don't think there is any reason not to do assembly. Learning is great. Learn all you can. Drop into a low enough level debugger and look at the disassembled code.
My advice is:
Don't be scared.