Back when webservices were going to take over the world, I stumbled upon xmethods.net. It's still around, but I can no longer vouch for it's accuracy or timeliness. Note the dated blurb:
Emerging web services standards such as SOAP, WSDL and UDDI will enable system-to-system integration that is easier than ever before.
Googling web services list points to a couple higher rated sites that you'd probably want to check out as well:
Personally, I've discovered that random, free web services are more trouble than they're worth. Pretty much anything they're doing*, I can more effectively and more reliably provide myself for minimal cost.
If I'm looking for a solution to a specific problem, eg. storing credit card data securely, then I'll evaluate the options in that space - web service or not.
- Notable exceptions include accessing proprietary data, such as CDDB or Amazon. But, if I need that data, a quick google will turn up who has high quality data - then it's on to find an API for it.