Open a terminal and type man gcc
Do you mean -mthumb-interwork ?
-mthumb-interwork
Generate code which supports calling between the ARM and Thumb
instruction sets. Without this option the two instruction sets
cannot be reliably used inside one program. The default is
-mno-thumb-interwork, since slightly larger code is generated when
-mthumb-interwork is specified.
If this is related to a build configuration, you should be able to set it separately for each configuration "such as Release or Debug".
Why do you want to change these settings? I know using thumb instructions save some memory but will it save enough to matter in this case?