xtype is a shorthand way to identify particular components: 'panel' = Ext.Panel, 'textfield' = Ext.form.TextField, etc. When you create a page or a form, you may use these xtypes rather than instantiate objects. For example,
items: [{
xtype: 'textfield',
autoWidth: true,
fieldLabel: 'something'
}]
Moreover, creating pages in this manner allows ExtJS to render lazily the page. This is where you see a "performance gain." Instead of creating a large number of components when the app loads, ExtJS renders components when the user needs to see them. Not a big deal if you have one page, but if you exploit tabs or an accordion, many pages are initially hidden and therefore the app will load more quickly.
Furthermore, you may create and register new components creating xtypes of your choosing. ExtJS will similarly render your components lazily.
You may also retrieve components by ID. Since your component (as well as the ExtJS components) may provide a bunch of nice behavior, it is sometimes convenient to search for and retrieve a component rather than a simple DOM element or node.
In short, xtypes identify components and components are a key aspect of ExtJS.