Try
XCOPY /U
/U will make it only copy files from the source to files in the destination, it won't copy any files that do not already exist (which is what I think you are asking for).
To copy files with the same names from c:\weebles to c:\wobble you would do
XCOPY c:\weebles c:\wobble /U /Y
Specify /U to only copy files that already exist in the destination
Specify /Y to copy without asking your permission to overwrite each file (will get tedious really quick).
For more info, open a command prompt and type
help xcopy
IMPORTANT: Before you try this (or a variant) do either:
- A backup of your destination folder
- A test on some folders that don't matter
Would be a shame to go all gung ho, start the copy then regret it! :-)