Three things.
1) What Timothy Walters said is right on, I'll go in to more detail.
2) 4500 files and 500Mb of data is simply a lot of data and disk writes. If you're operating on the entire dataset, it's going to be slow. Just I/O truth.
3) As others have mentioned, there's no detail on the use case.
If we assume a read only, random access scenario, then what Timothy says is pretty much dead on, and implementation is straightforward.
In a nutshell, here is what you do.
You concatenate all of the files in to a single blob. While you are concatenating them, you track their filename, the file length, and the offset that the file starts within the blob. You write that information out in to a block of data, sorted by name. We'll call this the Table of Contents, or TOC block.
Next, then, you concatenate the two files together. In the simple case, you have the TOC block first, then the data block.
When you wish to get data from this format, search the TOC for the file name, grab the offset from the begining of the data block, add in the TOC block size, and read FILE_LENGTH bytes of data. Simple.
If you want to be clever, you can put the TOC at the END of the blob file. Then, append at the very end, the offset to the start of the TOC. Then you lseek to the end of the file, back up 4 or 8 bytes (depending on your number size), take THAT value and lseek even farther back to the start of your TOC. Then you're back to square one. You do this so you don't have to rebuild the archive twice at the beginning.
If you lay out your TOC in blocks (say 1K byte in size), then you can easily perform a binary search on the TOC. Simply fill each block with the File information entries, and when you run out of room, write a marker, pad with zeroes and advance to the next block. To do the binary search, you already know the size of the TOC, start in the middle, read the first file name, and go from there. Soon, you'll find the block, and then you read in the block and scan it for the file. This makes it efficient for reading without having the entire TOC in RAM. The other benefit is that the blocking requires less disk activity than a chained scheme like TAR (where you have to crawl the archive to find something).
I suggest you pad the files to block sizes as well, disks like work with regular sized blocks of data, this isn't difficult either.
Updating this without rebuilding the entire thing is difficult. If you want an updatable container system, then you may as well look in to some of the simpler file system designs, because that's what you're really looking for in that case.
As for portability, I suggest you store your binary numbers in network order, as most standard libraries have routines to handle those details for you.