psoul's excellent post answers to your question so I won't replicate his good work, but I feel it'd help to explain why this is at once a perfectly valid but also terribly silly question. After all, this is a place to learn, right?
Modern computer programs are produced through a series of conversions, starting with the input of a human-readable body of text instructions (called "source code") and ending with a computer-readable body of instructions (called alternatively "binary" or "machine code").
The way that a computer runs a set of machine code instructions is ultimately very simple. Each action a processor can take (e.g., read from memory, add two values) is represented by a numeric code. If I told you that the number 1 meant scream and the number 2 meant giggle, and then held up cards with either 1 or 2 on them expecting you to scream or giggle accordingly, I would be using what is essentially the same system a computer uses to operate.
A binary file is just a set of those codes (usually call "op codes") and the information ("arguments") that the op codes act on.
Now, assembly language is a computer language where each command word in the language represents exactly one op-code on the processor. There is a direct 1:1 translation between an assembly language command and a processor op-code. This is why coding assembly for an x386 processor is different than coding assembly for an ARM processor.
Disassembly is simply this: a program reads through the binary (the machine code), replacing the op-codes with their equivalent assembly language commands, and outputs the result as a text file. It's important to understand this; if your computer can read the binary, then you can read the binary too, either manually with an op-code table in your hand (ick) or through a disassembler.
Disassemblers have some new tricks and all, but it's important to understand that a disassembler is ultimately a search and replace mechanism. Which is why any EULA which forbids it is ultimately blowing hot air. You can't at once permit the computer reading the program data and also forbid the computer reading the program data.
(Don't get me wrong, there have been attempts to do so. They work as well as DRM on song files.)
However, there are caveats to the disassembly approach. Variable names are non-existent; such a thing doesn't exist to your CPU. Library calls are confusing as hell and often require disassembling further binaries. And assembly is hard as hell to read in the best of conditions.
Most professional programmers can't sit and read assembly language without getting a headache. For an amateur it's just not going to happen.
Anyway, this is a somewhat glossed-over explanation, but I hope it helps. Everyone can feel free to correct any misstatements on my part; it's been a while. ;)