NoSQL has been getting a lot of attention in the industry recently. I'm really interested in what peoples thoughts are on the best use-cases for its use over relational database storage. What should trigger a developer into thinking that particular datasets are more suited to a NoSQL solution. I'm particularly interested in MongoDB and CouchDB as they seem to be getting the most coverage with regard to PHP development and that is my focus.
What I like about NoSQL has nothing to do with performance and everything to do with usability. Document stores are just easier to work with when your atomic data units are document-like, because it's trivial to serialize to and from objects. It's just more fun, and that's an important factor for personal or side projects.
I'd suggest this article by Rick Cattell about miscellaneous data stores (a.k.a. NoSQL), their differences and some of their use-cases: http://www.cattell.net/datastores/index.html
Just promise yourself that you will never try to map a relational data model to a NoSQL database like MongoDB or CouchDB... This is the most common mistake developers make when evaluating emerging tech.
That approach is analogous to taking a car and trying to use it to pull your cart down the road like a horse.
It's a natural reaction due to everyone's experience of course, but the real value in using a document database is being able to simplify your datamodel and minimize your suffering as a developer. Your codebase will shrink, your bugs will be fewer and easier to find, performance is going to be awesome, and scale will be much simpler.
As a Joomla founder I'm biased :-) but coming from the CMS space, something like MongoDB is a silver bullet as content maps very naturally to document systems.
Another great case for MongoDB is real-time analytics, as MongoDB has very strong performance and scale particularly regarding concurrency. There are case studies at the MongoDB.org website that demonstrate those attributes.
I agree with the notion that each database has its own aims and use cases; take the purpose of each database for evaluation accordingly.
Some great use-cases - for MongoDB anyway - are mentioned on the MongoDB site. The examples given are real-time analytics, Logging and Full Text search. These articles are all well worth a read http://www.mongodb.org/display/DOCS/Use+Cases