Here's how I solve this sort of problem without using a subquery:
SELECT s.*
FROM Schools AS s
JOIN Grades AS g1 ON g1.id_schools = s.id
LEFT OUTER JOIN Grades AS g2 ON g2.id_schools <> s.id
AND g1.Reading < g2.Reading
WHERE g2.id_schools IS NULL
Note that you can get more than one row back, if more than one school ties for highest Reading score. In that case, you need to decide how to resolve the tie and build that into the LEFT OUTER JOIN condition.
Re your comment: The left outer join looks for a row with a higher grade for the same school, and if none is found, all of g2.* columns will be null. In that case, we know that no grade is higher than the grade in the row g1 points to, which means g1 is the highest grade for that school. It can also be written this way, which is logically the same but might be easier to understand:
SELECT s.*
FROM Schools AS s
JOIN Grades AS g1 ON g1.id_schools = s.id
WHERE NOT EXISTS (
SELECT * FROM Grades g2
WHERE g2.id_schools <> s.id AND g2.Reading > g1.Reading)
You say it's not working. Can you be more specific? What is the answer you expect, and what's actually happening, and how do they differ?
edit: Changed =
to <>
as per suggestion in comment by @potatopeelings. Thanks!