I'm not sure I understand "a lot of insertions which hit the same entries". Do you mean that there are only 100 values which are ever members, but 500k mostly-duplicate operations which insert one of those 100 values?
If so, then I'd guess that the fastest container would be to generate a collision-free hash over those 100 values, then maintain an array (or vector) of flags (int or bit, according to what works out fastest on your architecture).
I leave generating the hash as an exercise for the reader, since it's something that I'm aware exists as a technique, but I've never looked into it myself. The point is to get a fast hash over as small a range as possible, such that for each n, m in your 100 values, hash(n) != hash(m).
So insertion looks like array[hash(value)] = 1;
, deletion looks like array[hash(value)] = 0;
(although you don't need that), and to enumerate you run over the array, and for each set value at index n, inverse_hash(n) is in your collection. For a small range you can easily maintain a lookup table to perform the inverse hash, or instead of scanning the whole array looking for set flags, you can run over the 100 potentially-in values checking each in turn.
Sorry if I've misunderstood the situation and this is useless to you. And to be honest, it's not very much faster than a regular hashtable, since realistically for 100 values you can easily size the table such that there will be few or no collisions, without using so much memory as to blow your caches.