A: 

Check out How do I get the MAC address of a network card using Delphi? - the questions already been asked and answered a few times on SO.

Will A
+2  A: 

@steve0, to retrieve the mac address of an Network Adapter you can use the WMI and the Win32_NetworkAdapterConfiguration Class and check the MACAddress property.

Check this code:

program WMI_MAC;

{$APPTYPE CONSOLE}


uses
  SysUtils
  ,ActiveX
  ,ComObj
  ,Variants;

 function VarToStrNil(Value:Variant):string;  //Dummy function to onvert an variant value to string
 begin
   if VarIsNull(Value) then
    Result:=''
   else
    Result:=VarToStr(Value);
 end;


Procedure GetMacAddress;
var
  objWMIService : OLEVariant;
  colItems      : OLEVariant;
  colItem       : OLEVariant;
  oEnum         : IEnumvariant;
  iValue        : LongWord;
  wmiHost, root, wmiClass: string;

  function GetWMIObject(const objectName: String): IDispatch;
  var
    chEaten: Integer;
    BindCtx: IBindCtx;//for access to a bind context
    Moniker: IMoniker;//Enables you to use a moniker object
  begin
    OleCheck(CreateBindCtx(0, bindCtx));
    OleCheck(MkParseDisplayName(BindCtx, StringToOleStr(objectName), chEaten, Moniker));//Converts a string into a moniker that identifies the object named by the string
    OleCheck(Moniker.BindToObject(BindCtx, nil, IDispatch, Result));//Binds to the specified object
  end;

begin
  wmiHost       := '.';
  root          := 'root\CIMV2';
  wmiClass      := 'Win32_NetworkAdapterConfiguration';
  objWMIService := GetWMIObject(Format('winmgmts:\\%s\%s',[wmiHost,root]));
  colItems      := objWMIService.ExecQuery(Format('SELECT * FROM %s',[wmiClass]),'WQL',0);
  oEnum         := IUnknown(colItems._NewEnum) as IEnumVariant;
  while oEnum.Next(1, colItem, iValue) = 0 do
  //if VarToStrNil(colItem.MACAddress)<>'' then //uncomment if you only want list the interfaces with mac adress
  //if colItem.IPEnabled then  // uncomment if you only want list the active interfaces
  begin
    WriteLn('Card Description '+VarToStrNil(colItem.Caption));
    WriteLn('MACAddress       '+VarToStrNil(colItem.MACAddress));
  end;
end;

begin
 try
    CoInitialize(nil);
    try         
      GetMacAddress;
      Readln;
    finally
    CoUninitialize;
    end;
 except
    on E:Exception do
    Begin
        Writeln(E.Classname, ': ', E.Message);
        Readln;
    End;
  end;
end.
RRUZ
A: 

Here is some code working well for any computer on your network - may try it to get your own, using '127.0.0.1' as IP:

function GetRemoteMacAddress(const IP: AnsiString): TSockData;
// implements http://msdn.microsoft.com/en-us/library/aa366358(VS.85).aspx
type
  TSendARP = function(DestIp: DWORD; srcIP: DWORD; pMacAddr: pointer; PhyAddrLen: Pointer): DWORD; stdcall;
const
  HexChars: array[0..15] of AnsiChar = '0123456789ABCDEF';
var dwRemoteIP: DWORD;
    PhyAddrLen: Longword;
    pMacAddr : array [0..7] of byte;
    I: integer;
    P: PAnsiChar;
    SendARPLibHandle: THandle;
    SendARP: TSendARP;
begin
  result := '';
  SendARPLibHandle := LoadLibrary('iphlpapi.dll');
  if SendARPLibHandle<>0 then
  try
    SendARP := GetProcAddress(SendARPLibHandle,'SendARP');
    if @SendARP=nil then
      exit; // we are not under 2K or later
    dwremoteIP := inet_addr(pointer(IP));
    if dwremoteIP<>0 then begin
      PhyAddrLen := 8;
      if SendARP(dwremoteIP, 0, @pMacAddr, @PhyAddrLen)=NO_ERROR then begin
        if PhyAddrLen=6 then begin
          SetLength(result,12);
          P := pointer(result);
          for i := 0 to 5 do begin
            P[0] := HexChars[pMacAddr[i] shr 4];
            P[1] := HexChars[pMacAddr[i] and $F];
            inc(P,2);
          end;
        end;
      end;
    end;
  finally
    FreeLibrary(SendARPLibHandle);
  end;
end;

This code is extracted from our freeware and open source framework, unit SynCrtSock.pas. See http://synopse.info/fossil

A.Bouchez