Any difference it may make is the order in which the arguments will be evaluated. a != b would conventionally evaluate a, then evaluate b and compare them, while b != a would do it the other way round. However, I heard somewhere that the order of evaluation is undefined in some cases.
It doesn't make a big difference with variables or numbers (unless the variable is a class with overloaded != operator), but it may make a difference when you're comparing results of some function calls.
Consider
int x = 1;
int f() {
x = -1;
return x;
}
int g() {
return x;
}
Assuming the operands are evaluated from left to right, then calling (f() != g()) would yield false, because f() will evalute to -1 and g() to -1 - while (g() != f()) would yield true, because g() will evaluate to 1 and f() - to -1.
This is just an example - better avoid writing such code in real life!