Well, to be pedantic there's no "declare before use rule" in C++. There are rules of name lookup, which are pretty complicated, but which can be (and often are) roughly simplified into the generic "declare before use rule" with a number of exceptions. (In a way, the situation is similar to "operator precedence and associativity" rules. While the language specification has no such concepts, we often use them in practice, even though they are not entirely accurate.)
This is actually one of those exceptions. Member function definitions in C++ are specifically and intentionally excluded from that "declare before use rule" in a sense that name lookup from the bodies of these members is performed as if they are defined after the class definition.
The language specification states that in 3.4.1/8 (and footnote 30), although it uses a different wording. It says that during the name lookup from the member function definition, the entire class definition is inspected, not just the portion above the member function definition. Footnote 30 additionally states though that the lookup rules are the same for functions defined inside the class definition or outside the class definition (which is pretty much what I said above).
Your example is a bit non-trivial. It raises the immediate question about member function definitions in nested classes: should they be interpreted as if they are defined after the definition of the most enclosing class? The answer is yes. 3.4.1/8 covers this situation as well.
"Design & Evolution of C++" book describes the reasoning behind these decisions.