There isn't much information to go by in your question, but it seems like you could use a macro to transform your data. I wrote a quick macro that takes data in the format you have presented and outputs it as you have specified.
I would use the macro below to create a new Worksheet in Excel and then manipulate it or paste it into Word as necessary. Without more information, there isn't more to say.
**Input**
Column A Column B
Result A1 Result B1
Result A2 Result B2
**Output**
Column A
Result A1
Column B
Result B1
Column A
Result A2
Column B
Result B2
Here is the macro:
' Transforms the current sheet
' This method takes columns and rows and outputs a
' single This is not a transpose method, but similar.
Public Sub TransformSheet()
Dim SourceSheet As Worksheet
Dim ResultSheet As Worksheet
Dim iSourceColumn As Long, iSourceRow As Long
Dim iResultColumn As Long, iResultRow As Long
Dim iHeaderRow As Long
Dim UseCopyPaste As Boolean
' Change source and result sheets as necessary
Set SourceSheet = ActiveSheet
Set ResultSheet = ActiveWorkbook.Sheets("Sheet2")
' Options
UseCopyPaste = True
iHeaderRow = 1
iResultColumn = 1
iResultRow = 1
' Main Loop
For iSourceRow = 2 To SourceSheet.UsedRange.Rows.Count
For iSourceColumn = 1 To SourceSheet.UsedRange.Columns.Count
If UseCopyPaste Then
' Header Column
SourceSheet.Cells(iHeaderRow, iSourceColumn).Copy
ResultSheet.Cells(iResultRow, iResultColumn).PasteSpecial xlPasteAll
iResultRow = iResultRow + 1
' Result Column
SourceSheet.Cells(iSourceRow, iSourceColumn).Copy
ResultSheet.Cells(iResultRow, iResultColumn).PasteSpecial xlPasteAll
iResultRow = iResultRow + 1
Else
' Header Column
ResultSheet.Cells(iResultRow, iResultColumn) = _
SourceSheet.Cells(iHeaderRow, iSourceColumn).Value
iResultRow = iResultRow + 1
' Result Column
ResultSheet.Cells(iResultRow, iResultColumn) = _
SourceSheet.Cells(iSourceRow, iSourceColumn).Value
iResultRow = iResultRow + 1
End If
Next iSourceColumn
Next iSourceRow
End Sub