I haven't used Windows 7, but if I recall correctly, there should be a way to start an explorer session (the filemanager, not IE) under the Postgres user and then remove it.
Otherwise, you might be able to, by logging in as an Administrator, add rights for Administrators to modify that directory and the parent directory and after that you should be able to remove it.
I am not certain if it is possible for an administrator to remove the directory directly, but it should be possible for one to add the rights to do so.
Update:
I just installed PostgreSQL and tested it in Vista, it might work the same in Windows 7.
It seems like they have fixed the permission stuff, so the tip above doesn't work (changing the permissions).
However, if the system account is still there, you can access it in the Computer Management.
Add it to a regular user group (like Users or Administrators) and then you should be able to login with it and after that remove the directory.