If this will be your primary developer make sure you have him provide you with proof of work that he has completed in the past. Look for someone that has done e-commerce type work and has created an end to end solution. Some people say they have made x, y, and z and then later you find out all they did was the HTML design or the DB work etc... you probably need someone that has done it all in one form or another.
Don't worry so much about technologies but make sure whoever you are hiring will use a technology that they have past experience with so they are not learning it on your dime. You probably don't want to pay for their 'research' assuming you are paying by the hour.
If your looking for a developer to start a start-up with you then all you need is a competent developer that has a passion for learning and a passion for the product the two of you will be producing.