If I wanted to create a string which is guaranteed not to represent a filename, I could put one of the following characters in it on Windows:
\ / : * ? | < >
e.g.
this-is-a-filename.png
?this-is-not.png
Is there any way to identify a string as 'not possibly a file' on Linux?
There are almost no restrictions - apart from '/' and '\0', you're allowed to use anything. However, some people think it's not a good idea to allow this much flexibility.
An empty string is the only truly invalid path name on Linux, which may work for you if you need only one invalid name. You could also use a string like "///foo", which would not be a canonical path name, although it could refer to a file ("/foo"). Another possibility would be something like "/dev/null/foo", since /dev/null has a POSIX-defined non-directory meaning. If you only need strings that could not refer to a regular file you could use "/" or ".", since those are always directories.