Ephemient: each child in your code will stay in the for loop after his job ends. He will fork again and again. Moreover, the children that start when children[] is not empty will try to wait for some of their brothers at the end of the loop. Eventually someone will crash. This is a workaround:
import os, time
def doTheJob(job):
for i in xrange(10):
print job, i
time.sleep(0.01*ord(os.urandom(1)))
# random.random() would be the same for each process
jobs = ["A", "B", "C", "D", "E", "F", "G", "H", "I", "J"]
imTheFather = True
children = []
for job in jobs:
child = os.fork()
if child:
children.append(child)
else:
imTheFather = False
doTheJob(job)
break
# in the meanwhile
# ps aux|grep python|grep -v grep|wc -l == 11 == 10 children + the father
if imTheFather:
for child in children:
os.waitpid(child, 0)