The first approach is to force programmers to only know interfaces of other components, so that each one can only steal a small part of the whole software. This approach can be borrowed from footwear production. One transnational corporation, to prevent stealing by employees, arranged its factories so that each factory produced only left or only right shoes. You could do the same with your code: some programmers only write lines with odd numbers, and the others--those with even numbers; provided that they can't see the work of each other! That's sometimes referred to as "pair programming".
Some organizations force employees to sign a non-compete agreement. That's the kind of agreement that prevents programmers to work for competitors. This technique is best combined with job postings like "Looking for senior programmer with 5 years of experience in the similar field".
To prevent your programmers from stealing, you can do harm to them as soon as they finish the software. The method proved itself as the most efficient, and has been used for centuries. For example, Russian Tzar Ivan The Terrible burned eyes of the architect that designed a beautiful church at the Red Square, so the one designed remains the most beautiful ever. You can do something like this to your architect. I heard, latest Visual Studio contains some features...
Nowadays, however, it's more humanistic to hire already blind and already dumb people that lost their hands, so that they can't look at your code to memorize it, can't tell anyone about your code and can't type it again. The advantage is that this will help you dealing with labor agency in your country, which watches for balance that your employees are not discriminated.
And yes, this post is a sarcastic joke, which criticizes the idea of any code-stealing-prevention measures. Sorry, couldn't help posting it.