Dealing with factors in R is quite peculiar job, I must admit... While reordering the factor levels, you're not reordering underlying numerical values. Here's a little demonstration:
> numbers = 1:4
> letters = factor(letters[1:4])
> dtf <- data.frame(numbers, letters)
> dtf
numbers letters
1 1 a
2 2 b
3 3 c
4 4 d
> sapply(dtf, class)
numbers letters
"integer" "factor"
Now, if you convert this factor to numeric, you'll get:
# return underlying numerical values
1> with(dtf, as.numeric(letters))
[1] 1 2 3 4
# change levels
1> levels(dtf$letters) <- letters[4:1]
1> dtf
numbers letters
1 1 d
2 2 c
3 3 b
4 4 a
# return numerical values once again
1> with(dtf, as.numeric(letters))
[1] 1 2 3 4
As you can see... by changing levels, you change levels only (who would tell, eh?), not the numerical values! But, when you use factor function as @Jonathan Chang suggested, something different happens: you change numerical values themselves.
You're getting error once again 'cause you do levels and then try to relevel it with factor. Don't do it!!! Do not use levels or you'll mess things up (unless you know exactly what you're doing).
One lil' suggestion: avoid naming your objects with an identical name as R's objects (df is density function for F distribution, letters gives lowercase alphabet letters). In this particular case, your code would not be faulty, but sometimes it can be... but this can create confusion, and we don't want that, do we?!? =)
Instead, use something like this (I'll go from the beginning once again):
> dtf <- data.frame(f = 1:4, g = factor(letters[1:4]))
> dtf
f g
1 1 a
2 2 b
3 3 c
4 4 d
> with(dtf, as.numeric(g))
[1] 1 2 3 4
> dtf$g <- factor(dtf$g, levels = letters[4:1])
> dtf
f g
1 1 a
2 2 b
3 3 c
4 4 d
> with(dtf, as.numeric(g))
[1] 4 3 2 1
Note that you can also name you data.frame with df and letters instead of g, and the result will be OK. Actually, this code is identical with the one you posted, only the names are changed. This part factor(dtf$letter, levels = letters[4:1]) wouldn't throw an error, but it can be confounding!
Read the ?factor manual thoroughly! What's the difference between factor(g, levels = letters[4:1]) and factor(g, labels = letters[4:1])? What's similar in levels(g) <- letters[4:1] and g <- factor(g, labels = letters[4:1])?
You can put ggplot syntax, so we can help you more on this one!
Cheers!!!
Edit:
ggplot2 actually requires to change both levels and values? Hm... I'll dig this one out...